| Jahr | Minister | König | Minister |
| 2000 | Norbert Maaßen | Ulrich Maaßen | Clemens Offergeld jun. |
| 2001 | Winfried Bollmann | Michael Günther | Charly Jansen |
| 2002 | Jacki Elsberger | Heinz Peter Roemer | Andreas Rayer |
| 2003 | Peter Walbergs | Rolf Thelen | Jürgen Ohlenforst |
| 2004 | Arno Oellers | Konrad Ohoven | Thomas Jendraszyk |
| 2005 | Harald Rütten | Ralf Lennartz | Volker Mandelartz |
| 2006 | Helmut Porta | Thomas Funken | Claus-Dieter Landolt |
| 2007 | Helmut Hansen | Matthias Schmickartz | Peter Feldhoff |
| 2008 | Thomas Goßmann | Michael Weuthen | Olaf Jestel |
| 2009 | Hans Rittger | Wilfried Kremer | Werner Camps |
| 2010 | Claus-Dieter Landolt | Helmut Porta | Thomas Funken |
| 2011 | Hans Rittger | Friedhelm Reuter | Wilfried Kremer |
| 2012 | Markus Zitzen | Jürgen Ohlenforst | Axel Klerx |
| 2013 | Hans Maahsen | Stefan Pohlen | Reiner Loos |
| 2014 | Stefan Bohnen | Uwe Grams | Adrian Wydra |
| 2015 | Harald Elsberger | Manuel Elsberger | Markus Elsberger |
| 2016 | Helmut Porta | Claus-Dieter Landolt | Thomas Funken |
| 2017 | Ingo Blasius | KAISER Friedhelm Reuter | Dominik Heck |
| 2018 | Leo Elsberger | KÖNIGIN Silke McCoy | Martin Kolonko |
| 2019 | Rainer Loos | Paul Wagner | Hans-Willi Dols |
| 2020/21/22 | Lothar Breimer | Guido Friedrich | Roger Kettenbach |
| 2023 | Daniela Pohlen | KÖNIGIN Elke Loos | Gerda Dols |
| 2024 | Alexander Köntges | Stephan Schumacher | Bastian Schüren |
| 2025 | Peter Blümel | Torsten Abels | Micha Richter |